Conference Abstracts

Abstract

Work is being conducted in Limpopo province following a large volume release of petroleum hydrocarbons that took place from a leaking underground pipeline, resulting in significant groundwater contamination. This is considered to be the largest petroleum hydrocarbon release recorded to date in South Africa. The leak took place for 15 years before it was discovered 13 years ago in 2000. From the pressure tests that were performed, 10-15 ML of A-1 Jet fuel is considered to have  been  released  to  the  subsurface.  Product  bailing was  the  first method  employed  for  the recovery of the free product, and was later replaced with a P&T system which was considered to be more effective.

The village located about 6 km to the north of the spillage depends mostly on groundwater. This paper presents a progress update of works that have been conducted in support of developing a conceptual model which aims to determine the areal extent of the plume.

Abstract

Vapour intrusion (VI) is the term used to define the encroachment of vapour phase contaminants from subsurface sources into structures such as buildings and basements. It is widely recognised that VI often forms the principal risk of exposure to receptors at petroleum release sites. Petroleum VI (PVI) generally occurs where a release of petroleum hydrocarbon product migrates from its source (for example, from a leaking underground storage tank) to the groundwater table at which point, given favourable conditions, the hydrocarbon plume may migrate laterally beneath an adjacent building or structure. Subsequent volatilisation of the petroleum product results in the upward diffusion of vapours towards the surface where the vapours may enter into the building or structure at concentrations which may be harmful to human health. The subject of PVI with regards to its fate and transport mechanisms, as well as associated mitigation measures, is rapidly gaining attention on a global scale, although to date this exposure pathway remains largely unassessed in South Africa, with no regulatory guidance currently available. In the late 1990s and early 2000s focus was placed on the development of VI screening criteria by which sites could be screened with respect to their hydrogeological conditions and contamination status so as to determine whether VI may be a potential exposure pathway of concern, with much of the early work being completed by the United States Environmental Protection Agency. For the past decade the majority of the available screening criteria  and  guidance  has  not,  or  has  only  partially  accounted  for  biodegradation  processes associated with VI, which has led to doubt over the application of such screening criteria in many cases. Furthermore, recent research conducted abroad has highlighted the importance of the role of oxygen in the vadose zone in the natural attenuation of petroleum hydrocarbon vapours as they diffuse through the soil profile. This research is pointing towards the notion that currently applied screening criteria may be overly conservative when applied to petroleum impacted sites, leading to many  unnecessary  PVI  investigations  being  conducted  to  the  disruption  of  occupants  of  the buildings, and at great cost. Over the last two years ERM has compiled a dataset of PVI results from numerous investigations it has conducted throughout Southern Africa and in this paper the authors present data that supports the growing global trend towards recognising the role that oxygen plays in attenuating petroleum hydrocarbon vapours in the vadose zone. The data also support the notion that confirmed cases of PVI into buildings have generally been found to be the exception to the rule and not the norm.

Abstract

POSTER The Evander Goldfield basin has been mined since the early 1950s at depths between 400 and 2 000 m below ground and is detached from the larger Witwatersrand basin. The assessment and prediction of mine water rebound has become increasingly important for the gold mining industry in the Witwatersrand basin as more mine shafts mothballs and dewatering ceases. The development of a  3-D  mine  void  model  is  crucial  in  predicting  the  rate  of  flooding  as  the  prediction  of  the groundwater rebound is primarily driven by the volumes of mine voids along with the amount of recharge. All available mine plan data for the Evander Gold Mine (EGM) were obtained digitally from Harmony Gold. However, the majority of the old mine workings (e.g. Leslie and Winkelhaak) were available  as  2-D  data  and  elevations  of  the  mine  developments  (stopes  and  drives)  had  to  be captured from hardcopy plans. Data from the more recent mining operations (e.g. Shaft 6), including updated survey and mine plan data, were directly used for the development of the 3-D void model. The calculated mine void volume, based on the EGM operations mine plan data, is approximately 80 518 045 m3. The mine void calculations were checked against the total tons of rock milled by the EGM operations since the late 1950s and was considered valid estimations of the EGM mine void volume. The validated EGM 3-D mine workings plan was subsequently used to determine the stage- volume relationships. The 3-D mine void model established, will then be incorporated into a regional numerical groundwater flow model to be calibrated against observed abstractions and water levels and utilised to predict future dewatering rates.

Abstract

Gold mining  activities over  the  past 60 years  in the Klerksdorp  goldfield produced  saline mine drainage that polluted water. Oxidation of sulphide material in tailings storage facilities, waste rock dumps and extraction plants is mobilised to produce saline mine drainage with sulphate, minor salts and  metals  that  seep  to  the  groundwater  and  ultimately  into  surface  water  resources.  Water regulation requires mines to prevent, minimise/reduce or eliminate pollution of water resources. The waste philosophy has matured from tolerate and transfer to treat and termination of pollution sources.  The  impact  of  the  pollution  was  determined  and  possible  technologies  to  treat  the impact   were   evaluated.   Source   controls   with   proper  water  management  by  storm  water management,  clean  dirty  water  separation,  lined  water  conveyance  structures  and  reduced deposition of water on waste facilities are crucial. The aquifer character determines the possible remediation technology. From the possible technologies phytoremediation, physical interception and  re-use  of  this  water  was  selected.  In  future  possible  treatment  of  the  water  would  be considered. This paper explain the strategy and report on the phased implementation of these plans and the expected results. The establishment of 500 ha of woodlands as phytoremediation, interception trenches of 1 000 m, 38 interception boreholes and infrastructure to re-use this water is planned. The total volume of 15 Ml/day would be abstracted for re-use from the boreholes and trenches. The woodlands can potentially attenuate and treat 5 Ml/day. The established woodlands of 150 ha prove to be successful to intercept diffused seepage over the area of establishment and reduce  the  water  level  and  base  flow.  The  two  production  interception  well- fields  that  are abstracting  50  and  30 l/s,  respectively  , indicate  a  water  level decline of between 2 to 14 m, with regional cones of depression of a few hundred meters to intercept groundwater flow up to a 20 m depth. Predictions from groundwater modelling indicate that these schemes can minimise pollution during the operational phase and protect downstream water resources. Predictions from modelling indicate that the pollution sources need to be removed to ensure long-term clean-up to return the land to safe use. The gold and uranium prize is securing the removal of the sources through  re-processing  of  the  tailings  and  waste  rock  dumps.  After  removal  of  the  sources  of pollution,  the  remediation  schemes  would  have  to  be  operated  for  20  years  to  return  the groundwater to an acceptable standard  of  stock  watering  and  industrial  water  use.  The  water quality is observed by a monitoring network of approximately 100 observation boreholes.

Abstract

The Paleozoicage Natal Group Sandstone (NGS) that outcrops from Hlabisa (in the north) to Port Shepstone (in the south) and Greytown (west) to Stanger (east) in the Province of KwaZulu-Natal, South Africa, is investigated in terms of its hydrogeological characteristics. This sandstone group, which comprises a lower Durban and an upper Marrianhill Formations, is a secondary/fractured aquifer system that has variable but good productivity across its members. It is characterised by variable borehole blow yields ranging from 0.2 l/s to as high as 20 l/s, with more than 50% of the boreholes having blow yield > 3 l/s. Preliminary analysis of these boreholes yields indicates that higher yielding boreholes are associated with a network of intersecting fractures and faults, and are recommended targets for future water well-siting in the area. Groundwater in the NGS is of good quality in terms of major and trace element composition and it has a total dissolved solids (TDS) composition of <450 mg/l. It was observed that the specific electrical conductivity (EC), TDS and major ions composition of groundwater within the sandstone decrease from north to south, which appears to be controlled by the geochemical composition of the aquifer material and an increase in the rate of recharge. Depth to groundwater is also found to decrease southwards because of an increase in the rate of recharge. Groundwater hydrochemical facies are generally either Na-HCO3 or Na-HCO3–Cl, and environmental isotope data (2H, 18O, Tritium) indicates that the groundwater gets recharge from modern precipitation. Furthermore, the EC increases from inland to the coastal zone, indicating maritime influences and the general direction of groundwater flow is eastwards, to the Indian Ocean.

Abstract

The increase in awareness of environmental issues and the desire for a cleaner environment by the public has caused mining companies to place greater emphasis on the continuous rehabilitation of harmful effects caused by mining operations. Ongoing rehabilitation is also a requirement of the government departments involved in mining in South Africa. The biggest concern for the relevant government departments is the possible uncontrolled pollution of water resources in the vicinity of mines, after they have closed.

In  the  compilation  of  this  paper,  the  unique  nature  of  the  South  African  situation  has  been considered – this refers to a legally acceptable approach towards current legislation and policies. This study leads to the construction of a logical approach towards mine closure, specifically to understand issues around costs and financial liability. The final product of this approach should ultimately give more clarity on:

the principles followed to identify objectives for mine closure and groundwater assessment;

key steps to follow when assessing site hydrogeology and to determine related impacts, risks, closure costs and liabilities; and

an overview of methods that could be used for the mitigation of polluted aquifers and a brief site-specific application.

Abstract

Many aquifer systems worldwide are subject to hydrochemical and biogeochemical reactions involving iron, which limit the sustainability of groundwater schemes. This mainly manifests itself in clogging of the screen and immediate aquifer with iron oxyhydroxides resulting in loss of production capacity. Clogging is caused by chemical precipitation and biofouling processes which also manifests in South African well-fields such as in Atlantis and the Klein Karoo. Both well-fields have the potential to provide a sufficient, good quality water supply to rural communities; however, clogging of the production boreholes has threatened the sustainability of the schemes as quality and quantity of water is affected. Rehabilitation of the affected boreholes using techniques such as the Blended Chemical Heat Treatment method does not provide a long-term solution. Such treatments are costly with varying restoration of original yields achieved and clogging recurs with time. Currently the research,  management  and  treatment  options  in  South  Africa  have  focused  on  the  clogging processes which are complex and site-specific, making it extremely difficult to treat and rectify. This project attempts to eliminate elevated concentrations of dissolved iron, the cause of the clogging. High iron concentrations in groundwater are associated with reducing conditions in the aquifer allowing for the dissolution of iron from the aquifer matrix. These conditions can be natural or human-induced. Attempts to circumvent iron clogging of boreholes have focussed on increasing the redox potential in the aquifer, by injection of oxygen-rich water into the system, to prevent dissolution and to facilitate fixation of iron in the aquifer matrix. Various in situ treatment systems have  been  implemented  successfully  overseas  for  some  time.  In  South  Africa  thus  far  in  situ treatment of iron has only been proposed as a solution for production borehole clogging. Based on experience from abroad the most viable option to research the elimination of ferrous iron in South African aquifer systems would be through the in situ iron removal treatment. Different techniques of increasing the dissolved oxygen concentration in the injected water to intensifying the redox change in the aquifer can be applied; however, the use of ozone as the oxidant is a new approach. Its effectiveness is evaluated by the results in iron removal in surface water treatment for drinking water supply.

Abstract

This study examined the effective use of the hydrogeologic conceptual model (HCM) to implement the integrated water resource management (IWRM) approach. While research focuses on using hydrogeologic models  in  groundwater  for  planning,  few  studies  show  how  to  use  HCM  for  a successful IWRM approach, especially in  resource  poor  catchments.  This  is  largely  due  to  t he lack of adequate data to showcase such models. Despite the lack of numerical groundwater data, the HCM was used in this study and it provided the scientific and visual presentation of key issues for practical understanding by stakeholders. For the first time, HCM provided a  practical understanding of t he  groundwater system in the Limphasa River catchment. By using HCM and physical factors qualitatively, the study revealed that, apart from storage, abstraction mechanisms significantly contributes to regional initiatives of groundwater supply whose central objective is to utilise and manage such water sustainably. The model is based on the relationship between groundwater availability  and  its  related  hydrogeologic factors.  Findings suggest improvement  in quantifying the studied parameters through field experiments to provide a better estimation on storage and abstraction of groundwater in relation to impacts of a future changing climate. Since using HCM has shown practical usage, replicating it in catchments with similar physical and socioeconomic environments, would be desirable as refining the model progresses.

Abstract

The occurrence of groundwater around a mined-out open pit, connected to an active underground working is not completely understood, but it is fascinating. It has been established that gold mineralisation in study area was structurally controlled. The geomorphology of the local drainage system is highly controlled by the fold or fault architecture. Surface water flowed through, and eroded open fractures in exposed damaged zones (zone of subsidiary structures surrounding a fault). Previous  conceptual  hydrogeological models  of  groundwater  system  suggested  is  a  two-aquifer system, consisting of a fractured aquifer overlain by a weathered aquifer, where groundwater flow mimics surface topography. Based on recent drilling and reassessment of historic geological and hydrogeological data, the groundwater system around the mine could not only be described in terms of an elevation or stratigraphic units, as traditional aquifers are. The weight of the study was placed on accurately understanding the groundwater system in the deposit area by using structural hydrogeology as a best tool in the hydrogeological tool box. From a hydraulic head point of view, in addition to the weathered groundwater system, there are as many bedrock aquifers and aquitards as there are major structures in the pit area.

Abstract

Edible vegetable oil (EVO) substrates have been successfully used to stimulate the in situ anaerobic biodegradation of groundwater contaminated with chlorinated solvents, as well as numerous other anaerobically biodegradable contaminants like nitrates and perchlorates at many commercial, industrial and military sites throughout the world. EVO substrates are classified as a slow release fluid substrate, and comprise of food-grade vegetable oil such as canola or soya bean oil. The EVO substrate serves as an easily biodegradable source of carbon (energy) used to create a geochemically favourable environment for the anaerobic microbial communities to degrade specific contaminants of concern. EVO substrate’s can either be introduced into the subsurface environment as pure oil, in the form of light non-aqueous phase or as an oil/water emulsion. The emulsified vegetable oil substrates has several benefits over non-emulsified vegetable oil as the fine oil droplet size of the commercially manufactured emulsified oils can more easily penetrate the heterogeneous pore and fracture spaces of the aquifer matrix. The use of this technology to stimulate in situ biodegradation of groundwater contaminants is still relatively unknown in South Africa. This paper gives an overview of  the  EVO  technology  and  its  application,  specifically  looking  at  the  advantages  of  using  this relatively inexpensive, environmentally-friendly based technology to remediate contaminated groundwater within fractured rock environments commonly encountered in South Africa.

Abstract

South Africa currently ranks number nine in the world of the proved coal reserves that has been estimated to last for over 200 years. Coal constitutes about 77% of the primary energy needs in the country, with the Waterberg Coalfield estimated to host about 40% of the remaining South African coal resources. Coal deposits in the study area largely consist of shales, mudstones, siltstones and sandstones which host coal-containing clay minerals; quartz, carbonates, sulphides and the most abundant sulphide mineral is pyrite. Once mining begins, the sulphide minerals are exposed to surface which allows contact with atmospheric oxygen and water causes oxidation to take place, therefore causing acid-mine drainage (AMD). Acid-base accounting (ABA) was used to determine the balance between the acid-producing potential (AP) and acid-neutralising potential (NP). From the analysis the Net Neutralising Potential (NP-AP) was determined, which is one of the measurements used to classify a sample as potentially acid or non-acid-producing. Mineralogical analyses will be done by x-ray defraction (XRD) to define and quantify the mineralogy of the geological samples which can help in the management plan to minimise generation of acid. AMD does not only result in the  generation of acid, but as well as in decreased pH values and increased values of specific conductance, metals, acidity, sulphate, and dissolved and suspended solids. Inductively coupled plasma analysis was done to determine the release of the heavy metals which can be detrimental to the environment. Sample analysis was done on the interburden, overburden as well as the coal samples. From results obtained, over 35% to 50% of the samples have an excess of acid potential which classifies the samples as having a higher risk for acid generation. About 30% to 40% of the samples have a higher neutralising potential; the rest of the samples have a medium acid risk generation. The water demand will increase as developments continue in the  area, with inter- catchment transfers identified as the answer to fill the gap of water scarcity. Acid mine drainage poses a big threat on water resources, both groundwater and surface water nationally, which might be less of a problem in the Waterberg because of the cycle of low rainfall in the area, but the potential of AMD cannot be neglected.

Abstract

A multi-data integration approach was used to assess groundwater potential in the Naledi Local Municipality located in the North West Province of South Africa. The geology comprised Archaean crystalline basement, carbonate rocks (dolomite and limestone) and windblown sand deposits of the Kalahari Group. The main objective of the study is to evaluate the groundwater resource potential using multi-data integration and environmental isotope approaches. Prior to data integration, weighting coefficients were computed using principal component analysis.

The results of integration of six layers revealed a number of groundwater potential zones. The most significant zone covers ~14% of the study area and is located within carbonate rocks in the southern part of the study area. The localisation of high groundwater potential within carbonate rocks is consistent with the results of principal component analysis that suggests that lithology significantly contributed to the total data variance corresponding to principal component 1. In other words, carbonate rocks consisting of dolomite and limestone largely account for groundwater occurrence in the southern part of the area. In addition, the relatively elevated isotopic signature of tritium (≥1.0 TU)  in  groundwater  samples  located  in  the  southern  part  of  the  area  suggests  a  groundwater recharge   zone.   Furthermore,   moderate-to-good   groundwater   potential   zones   within   the Ventersdorp lava coincide with maximum concentration of fractures, which is consistent with the results of statistical correlation between borehole yield and lineament density. The multi-data integration approach and statistical correlation used in the context of evaluating groundwater resource potential of the area provided a conceptual understanding of hydrogeological parameters that control the development of groundwater in crystalline and carbonate rocks. Such approach is crucial in light of the increasing demand for groundwater arising from municipal water supply and agricultural use. The two approaches are very effective and can be used as a sound scientific basis for understanding groundwater occurrence elsewhere in similar hydrogeological environments.

Abstract

The possibility of large reserves of shale gas underlying the Karoo and their exploitation has focused attention on the groundwater resources and aquifers of this region. Much is known about the relatively shallow aquifers (<300 m) which supply many local municipalities and farmers with water for domestic, stock and irrigation use (mostly from boreholes <150 m in depth). Conversely, little is known about the deeper formations (>500 m) and associated groundwater occurrences and their possible interconnection to the shallow aquifer systems. This paper covers a desk study of the southern Karoo, mostly above the Great Escarpment, carried out by a group of hydrogeologists/geochemists with a cumulative experience of about 250 years. The main consideration at this stage has been the collation and analysis of existing information, using GIS, conceptualisations, and identification of knowledge gaps.

A Karoo Groundwater Atlas was published in 2012 and Volume 2 has been released at this conference, which present a summary of the main analyses. Borehole yield, recharge and quality in the shallow aquifer tend to improve, and water levels become shallower, from west to east, associated with higher rainfall and increased percentage of dolerite and sandstone. Aquifer yield, quality, lithology and presence of dolerites constitute 60% of a groundwater attributes ratings classification; 54% of the study area has a high rating. Twenty four percent of the study area has a high vulnerability rating. Knowledge of the characteristics of groundwater associated with the deeper formations is restricted to a few thermal springs and sparse data from some deep hydrocarbon exploration wells. Weak artesian flows were recorded from two such wells in the Dwyka Group below the Great Escarpment, with Total Dissolved Solids of up to 10 000 mg/L and temperatures of up to 77 oC, from depths of 2 347 to 3 100 m. Further work and cooperation with other researchers/institutions is on-going and planned to fill in knowledge gaps and assess the risks to groundwater of shale gas exploration.

Abstract

Groundwater in South Africa is an essential source of potable water for rural communities, farms and towns. Semi-arid conditions of South Africa, a growing population and surface water resources almost entirely being exploited to their limits, increase  the demand for groundwater resources. Therefore,  the  relation  between  the  geology  and  geohydrology  of  South  Africa  becomes  an important tool in locating groundwater resources that can provide sustainable quantities of water for South Africans. A document was therefore compiled, providing valuable geohydrological information  on  the  geological  formations  of  the  whole  of  South  Africa.  The  information  was gathered by means of interviews with experienced South African geohydrologists and reviewing of reports and articles of geohydrological studies. The geohydrological characteristics discussed include rock/aquifer parameters and behaviour, aquifer types (primary of secondary), groundwater quality, borehole yields and expected striking depths, and geological target features and the geophysical method  used  to  locate  these  targets.  Due  to  the  fact  that  90%  of  South  Africa’s  aquifers  are classified as secondary aquifer systems, groundwater occurrence within the rocks of South Africa is mainly controlled by secondary fractured systems; therefore, understanding the geology and geological processes (faulting, folding, intrusive dyke/sills and weathering) responsible for their development and how they relate, is important. However, the primary aquifers of South Africa (Coastal Cenozoic Deposits) should not be neglected as these aquifers can produce significant amounts of groundwater. Drilling success rates and possibility of striking higher yielding boreholes can be improved dramatically when an evaluation of the structural geology and geohydrological conditions of an area together with a suitable geophysical method is applied. The ability to locate groundwater has been originally considered (even today) a heavenly gift and can be dated back to the Biblical story of Moses striking the rock to get water: “behold, I will stand there before thee there upon the rocks thou shalt smite the rock and there shall come water out of it” (Exodus 17:6).

Abstract

The benefits of numerical groundwater modelling in resource management and scenario-testing are well known; it provides quantitative predictions of aquifer responses to stresses not yet experienced, albeit with uncertainties. Modelling is hence a widely used tool in Environmental Impact Assessment (EIA), in which prior to project commencing, the likely impacts must be assessed quantitatively to determine their significance. Based on these results mitigation measures can be proposed such that the residual impact is deemed acceptable.

At the stage of an EIA there is often very little data on which to base a model. Generally one is required to predict timescales in the order of hundreds of years with only very short-term time series data, and required to predict the response to stresses far beyond those used in the calibration. The very nature of the problems posed at EIA stage therefore render the accuracy of most modelling conducted at EIA phase severely limited. Recognising this, an appropriate model for the problems at hand can still be constructed and provide useful results.

The model results need to  be seen  as  the first phase  in  an  adaptive management cycle, rather than  a standalone prediction which a mine can use for future operation. To strengthen the resulting predictions, the cycle in which monitoring results are used to update the model, and thus update predictions and update future requirements for monitoring repeating the cycle, needs to be entrenched into the mine phases by ensuring the recommendation as detailed in the Environmental Management Plan. Thus, what started as a useful demonstrative tool, but with large uncertainties, becomes an accurate quantitative prediction tool for operation, closure and post-closure planning.

This paper outlines a case study of a proposed open-pit zinc mine on an inselberg in South Africa, within which these themes are explored. Limited initial data was sufficient to build a useful yet simplified model. The purpose and known limitations of the model approach dictated the spatial discretisation of the model, its dimensions, and the geometry of the aquifer units, yet the simplification of the aquifer systems into the numerical model was only feasible once the complexity of the aquifer systems had been recognised, else over- or unjustified simplification is a risk.

The paper concludes with a framework for integrating the adaptive groundwater management into the mine life cycle through applying appropriate models at each phase, which would strengthen the use of groundwater models in mining.

Abstract

Historically groundwater exploration consisted of reconnaissance geophysical surveys followed by detail ground surveys. Where no potentially water-bearing geological structures are shown on geological maps and aerial photos, the project area would be divided into a grid on which the ground geophysical survey would be done. This type of exploration is time-consuming and expensive. In some cases the terrain or cultural noise prohibits the use of conventional geophysical methods, with only more expensive and time-consuming methods being left as an option. This is where the high resolution airborne magnetic survey excels. The results obtained from this type of survey are of such a nature that ground geophysical surveys are only performed where potential drilling targets were identified  from  the  aerial  survey.  Not  only  can  there  be  cost-  and  time-savings  on  ground geophysical surveys, but drilling of dry boreholes can be limited, which makes up the largest cost component of a groundwater exploration project. This paper will discuss successes achieved using high resolution aeromagnetic surveys as the basis for groundwater exploration in traditionally low- yielding igneous geology.

Abstract

The National Environmental Management Waste Act, 59 of 2008 (NEMWA) clearly identifies the status and risk of contaminated sites and provides a legislative mechanism for remediation activities to be implemented and controlled. The Draft National Framework for the Management of Contaminated Land (henceforth Framework) provides national norms and standards for the practical implementation of remediation activities in compliance with NEMWA. A soil-screening value (SSV) for the protection of water resources is based on a two-phase equilibrium partitioning and dilution model which includes a dilution factor (DF) and partitioning coefficient (Kd) which converts the water quality guideline to a total soil-screening value. This paper presents a methodology to use soil-specific Kd  values to improve the accuracy of the new South African guideline for contaminated land.

Appropriate Phase 1 screening assessments are important due to the potential consequence it holds. Some uncertainty exists in the Phase 1 screening values due to variability in Kd values for different soil. This study shows that the Kd  values selected for the Framework is not representative of typical South African soils. Cu Kd values exceed the value provided by the Framework in all soils, but are lower that the Framework V Kd value in all soils. For Pb, low clay content weathered soils have lower Kd, but higher clay content soils are up to four orders of magnitude higher that the Kd in the Framework. Furthermore, due to the large variability (three to four orders of magnitude for Cu and Pb) point estimates of a single Kd value cannot be used for all soil types. However, for V only one order of magnitude variation is found. 

A way of addressing the uncertainty would be to determine the water soluble portion during the assessment. This would dramatically increase the certainty with which screening is conducted and could prevent significant inappropriate screening. Additional cost incurred be offset by saving as a result of unnecessary Phase 2 assessments or the reduction of undetected risks that later could impact the environment. 

Phase 1 screening could also be improved by including soil classification and some basic soil properties in the site assessment and adjusting Kd values, accordingly. Soil properties that can be used are typically clay content, pH and organic matter content. From these properties more appropriate Kds can be estimated for use in setting screening values.

Abstract

Most of the 14 651 km2 Hwange National Park in Zimbabwe is on monotonous Aeolian sands of the Kalahari Basin, with endorheic drainage. The large game populations of the park are sustained by seasonal accumulations of water in grassy pan depressions and year-round supply of groundwater to pans (except in the northwest where there are rivers and dams). Some of this is from natural seeps, such as at the Shakwanki, Nehimba and Ngweshla Pans, but most are supplied from boreholes. Game animals show clear preferences for some pans over others and it has long been speculated by wildlife managers that there is a nutritional or taste basis for this discrimination. In this preliminary study, the location, host geology and sub-Kalahari lithologies of the pans are compared with the frequency of use by game animals. Results show that the pans that are most frequented by game are hosted in fossil drainage channels, with limestone horizons (calcrete) developed within the Kalahari Sands. Many popular pans are also found on Kalahari Sand overlying the granitic rocks and the meta- sedimentary Malaputese Formation of the Kamativi–Dete Inlier. This can be related to sodium and potassium enrichment.

Abstract

The Sagole hot spring is located in the northern Limpopo Province of South Africa. Investigations were carried out in order to investigate the groundwater aquifer and water chemistry. Results were envisaged to the understanding of the geothermal potential of the area. Regional scale airborne magnetic data and geology were used for identifying structures and lithological boundaries that are associated with thermal groundwater aquifers. Detailed ground follow-up and verification surveys were  carried  out  across  the  target,  using  magnetic,  electrical  resistivity  tomography  (ERT), frequency-domain electromagnetic (FDEM) and radiometric methods. Water samples were collected from the spring eye and archival groundwater data was analysed. The interpretation of the airborne magnetic data revealed the presence of west to east, northwest and intersecting lineaments at the hot spring. From magnetic data, the groundwater aquifer was found to be capped by basalt with heat rising to the surface along possible geological contacts, faults or fractures. The FDEM profile data across the aquifer zone had peak values above 100 mS/m. The inversion of ERT data defined a highly electrical conductive, low resistivity with thickness of about 60 m. Chemical analysis of the ground water revealed that the water does not have any indication of pollution. The thermal water was found to be of meteoric origin. The drilling of artesian thermal boreholes through the capping basalt should be explored. The hot-water boreholes will be utilised by the community for domestic, irrigation and possible development of micro-geothermal systems.

Abstract

POSTER A quick analysis of spring water quality was conducted in four neighbouring villages, namely Vondo, Matondoni, Maranzhe and Murangoni in Thohoyandou town under the Thulamela Local Municipality (TLM) of the Vhembe District Municipality (VDM). For the purposes of this study these villages will be termed VMMM villages. A study on the spring water quality of VMMM villages was conducted by the CSIR to determine whether the natural quality state of the spring water used by the surrounding communities was suitable for drinking purposes without pre-treatment. From the four springs that were identified in the VMMM villages, namely Tshali (S1), Ramufhufhi (S2), Tshinwela (S3) and Tshivhase (S4), water samples were taken for the quality analyses in the laboratory. The results indicated that S2 and S4 had a high coliform count of 35 and 600 per 100 ml, respectively), that is above  10  counts  per  100 ml.  In  springs  S2  and  S4  the  total  coliform  count  also  displayed  the presence of E.coli (6 and 310 per millilitre, respectively)  – E.coli should not be detected at all according to SANS standard limits (2011). While all other parameters were within standard limits (SANS 241, 2011), it was also interesting to note that both S3 and S4 had a problem of high turbidity (1, 6 and 105 NTU, respectively) compared to 1 NTU which is the standard limit (SANS 241, 2011). These results showed that although these communities relied on groundwater in the form of springs for drinking purposes, unmonitored use of these resources may be a health hazard that has a potential to  result  in disease outbreak  and  unprecedented  deaths. While  groundwater through springs is considered natural, increased activity around the source due to human activity and interference by domestic animals, these sources may be rendered unsafe for drinking purposes without prior treatment. Therefore, there is need for local authorities to put measures in place to monitor water resources considered indigenous and traditional to the communities, especially in areas where these resources have become the main source of water supply for drinking purposes.

Abstract

The assessment and prediction of mine water rebound has become increasingly important for the gold mining industry in the Witwatersrand basin, South Africa. The cessation of dewatering lead to large volumes of contaminated surface discharges in the western parts of the basin. Towards the eastern extremity of the Witwatersrand basin the detached Evander Goldfield basin has been mined since the early 1950s at depths between 400 and 2 000 m below ground, while overlain by shallower coal mining operations. The hydrogeology of the Evander basin can be categorised by a shallow weathered-fractured rock aquifer comprising of the glacial and deltaic sediments of the Karoo Supergroup, while the deeper historically confined fractured bedrock aquifer consist predominantly of quartzite with subordinate lava, shale and conglomerate of the Witwatersrand Supergroup. The deep Witwatersrand aquifer has been actively dewatered for the last 60 years, with a peak rate of 60 Ml per day in the mid late 1960s. Modelling the impacts of mine dewatering and flooding on a regional scale as for the Evander basin, entails challenges like the appropriate discretisation of mine voids  and  the  accurate  modelling  of  layered  aquifer  systems  with  different  free  groundwater surfaces on a regional scale. To predict the environmental impacts of both the historic and future deep mining operations at Shaft 6, the detailed conceptual model of the aquifer systems and three- dimensional model of the mine voids were incorporated into a numerical groundwater model to simulate the dewatering and post-closure rebound of the water tables for the basin. The presented model could serve as an example for the successful modelling of mine dewatering and flooding scenarios for other parts of the Witwatersrand basin.

Abstract

Groundwater is the water that is found beneath the surface of the ground in a saturated zone (Bear 1979). Groundwater contamination refers to the groundwater that has been polluted commonly by human activities to the extent that it has higher concentrations of dissolved or suspended constituents. The scale of the potential supply of groundwater from the Cape Flats Aquifer Unit (CFAU) is very significant due to the increase of the population in Cape Town that leads to limited water resources (Maclear 1995). Groundwater contamination is a threat in the Cape Flats. This is because sand is more susceptible to pollution as a result of urbanisation, industrialisation, intense land use area for waste disposal and agricultural activities (Adelana 2010). The aim of this paper is to evaluate groundwater contamination and assess possible prevention and treatment measures in the CFAU. Pumping tests were done in UWC site in Borehole 5 (pumping borehole) and Borehole 4 (observation borehole) for six hours; three hours was for the pumping and the other three hours for recovery. This was done in order to see how the aquifer recovers after pumping. Water samples were also taken and analysed in the lab. This was done to find the type of contamination, whether it is degradable or non-degradable. The Borehole 5 drawdown plot is showing a straight line. This suggests a linear flow and that there is no confining bed beneath. This is because straight lines are showing the Cooper-Jacob type curve, which is for unconfined aquifers. The curve of Borehole 4 can be fitted to a Theis-type curve. This suggests a radial flow pattern indicating homogeneous characteristics in the deeply weathered zone and that there is a confining bed beneath. This is because aquifers responding in the same manner as the Theis-type curve, are confined aquifers (Hiscock 2005).The groundwater samples are showing a TDS range of 260 to 1 600 mg/l. This could be the result of the waste water treatment plant that is near UWC and the industries that are near the airport and at Bellville South. In conclusion, the geology of the CFAU is very susceptible to groundwater contamination, which is due to agricultural, industrial and human activities.

Abstract

This study explores some of the principle issues associated with quantifying surface  water and groundwater interactions and the practical application of models in a data scarce region such as South Africa. The linkages between the various interdependent components of the water cycle are not well understood, especially in those regions that suffer problems of data scarcity, and there remain  urgent  requirements  for  regional  water  resource  assessments.  Hydrology  (both  surface water and groundwater hydrology) is a difficult science; it aims to represent highly variable and non- stationary processes which occur in catchment systems, many of which are unable to be measured at the scales of interest. The conceptual representations of these processes are translated into mathematical form in a model. Different process interpretations, together with different mathematical representations, result in the development of diverse model structures. These structural uncertainties are difficult to resolve due to the lack of relevant data. Further uncertainty is introduced  when  parameterising  a  model,  as  the  more  complex  the  model,  the  greater  the possibility that many different parameter sets within the model structure might give equally acceptable results when compared with observations. Incomplete and often flawed input data are then used to drive the models and generate quantitative information. Approximate implementations (model structures and parameter sets), driven by approximate input data, will necessarily produce approximate results. Most model developers aim to represent reality as far as possible, and as our understanding of hydrological processes has improved, models have tended to become more complex. Beven (2002) highlighted the need for a better philosophy toward modelling than just a more explicit representation of reality and argues that the true level of uncertainty in model predictions  is  not  widely  appreciated.  Model  testing  has  limited  power  as  it  is  difficult  to differentiate  between  the  uncertainties  within  different  model  structures,  different  sets  of alternative parameter values and in the input data used to run a model. A number of South African case studies are used to examine the types of data typically available and explore the extent to which a model is able to be validated considering the difficulty in differentiating between the various sources of uncertainty. While it is difficult to separate input data, parameter and structural uncertainty, the study found that it should be possible to at least partly identify the uncertainty by a careful examination of the evidence for specific processes compared with the conceptual structure of a specific model. While the lack of appropriate data means there will always be considerable uncertainty surrounding model validation, it can be argued that improved process understanding in an environment can be used to validate model outcomes to a degree, by assessing whether a model is getting the right results for the right reasons.

Abstract

The significance of a reliable groundwater resource assessment is of growing importance as water resources are stretched to accommodate the growing population. An essential component of a groundwater resource assessment is the quantification of surface water–groundwater interaction. The  insufficient  amount  of  data  in  South  Africa  and  the  apparent  lack  of  accuracy  of  current estimates of the groundwater component of baseflow lead to the investigation of a new method. This applicability of this new approach, the Mixing Cell Model (MCM), to quantify the groundwater contribution to baseflow is examined to assess whether the method would be of use in further groundwater resource assessments. The MCM simultaneously solves water and solute mass balance equations  to  determine  unknown  inflows  to  a  system,  in  this  application  the  groundwater component of baseflow. The incorporation of water quality data into the estimation of the surface water–groundwater  interaction  increases the  use of  available  data,  and  thus has  the  ability to increase the confidence in the estimation process. The mixing cell model is applied to datasets from the surface water–groundwater interaction test site developed by the University of the Free State, in addition to data collected along the middle Modder River during a fieldwork survey. The MCM is subsequently applied to a set of quaternary catchments in the Limpopo Province for which there are available calibrated estimates of the groundwater component of baseflow for the Sami and Hughes models. The MCM is further applied to the semi-arid quaternary catchment D73F to assess the applicability of the mathematically-based MCM in a flow system within a regionally-defined zero groundwater  baseflow  zone.  The  results  indicate  that  the  MCM  can  reliably  estimate  the groundwater component of baseflow to a river when sufficient data are available. Use of the MCM has  the  potential  to  evaluate  as  well  as  increase  the  confidence  of  currently  determined groundwater baseflow volumes in South Africa, which will in turn ensure the responsible and sustainable use of the countries water resources.

Abstract

Work is being conducted in Limpopo province following a large volume release of petroleum hydrocarbons that took place from a leaking underground pipeline, resulting in significant groundwater contamination. This is considered to be the largest petroleum hydrocarbon release recorded to date in South Africa. The leak took place for 15 years before it was discovered 13 years ago in 2000. From the pressure tests that were performed, 10-15 ML of A-1 Jet fuel is considered to have  been  released  to  the  subsurface.  Product  bailing was  the  first method  employed  for  the recovery of the free product, and was later replaced with a P&T system which was considered to be more effective.

The village located about 6 km to the north of the spillage depends mostly on groundwater. This paper presents a progress update of works that have been conducted in support of developing a conceptual model which aims to determine the areal extent of the plume.

Abstract

Southern Africa hosts over 93% of the continent's energy, which has been conserved in coal seams deposited  in  various  Karoo  age  sedimentary  basins.  Carbon  dioxide  geological  storage  (CGS)  is proving  to  be  an  emerging  greenhouse  gas  technology  (GHGT),  that  global  governments  have elected to mitigate the projected coal use in Southern Africa. One of the major challenges of successfully introducing CGS to the public and world leaders is the significant risk the technology poses to groundwater resources. Lack of public confidence is further coupled by the poor knowledge of the subsurface behaviour of injected media, such as CO2, in South African potential lithological reservoirs. The study has utilised data from a current MSc research, in which the Springbok Flats Coal Basin (SFCB) has been used as the problem set-up. The aim of this study is to determine which FELOW™ mesh  geometry would  be  the most  suitable  to  simulate  a  CO2   ingress plume within  a regional aquifer. The study has utilised principals of dense vegetation zones (DVZ) and density- variable fluid flow (DVFF) when simulating the ingression. The specific objective is to utilise the simulation  results  to  guide  amendments  of  water  legislature,  towards  accommodating  CO2 geological  injection  and  storage operations.  Results indicate  that  a  combination  of  high-quality triangular meshes of various geometries, created with the FEFLOW compatible mesh generator, TRIANGLE, produced the best 3D model and simulation results. The basic matrice unit for the DTZ was defined as a quad mesh composed of two right-angled triangles and one equi-angualar triangle (five nodes), while the unit for modelling springs was defined as a quad mesh with four-equi-angular triangles, both used in various scales. The results were used to amend the Stream Flow Reduction Activities (SFRA) policy and thus the aquifer licensing procedure of the National Water Act, in order to accommodate the allocation of aquifer use licenses for CO2  geological storage operations. The amendments illustrate the significance of finite element simulation codes for integrated water resources management policy.

Abstract

A new mining site situated near Kolwezi in the Democratic Republic of the Congo plans to develop a pit in phases over a period of six years. The mine requires dewatering volume estimates of the pit as well as a constant water supply to the plant. Hydrogeologic data available at the site during the scoping phase was limited to a few water level measurements and blowout yields from only five hydrological boreholes. Hydraulic properties from reports at neighbouring sites were extrapolated to the geological units at the site. The depth to water level at the site is about 20 m, with a planned final pit depth of approximately 180 m below surface.

Based on the limited data available an analytical approach to estimate the inflow into the mine was adopted. Analytical calculations proposed by Marinelli and Niccoli (2000) were used to estimate the inflow into the Pumpi mine pits. The analytical calculations consider recharge, depth of mining vertical and horizontal hydraulic conductivities. Drawdown evolution of pit dewatering are obtained by using different mining depths at different mine stages. The output results from the analytical calculations are the maximum extent of influence of the pit as well as the volume of water inflow into the pit. Limitations of the analytical equations are that they, amongst others, cannot consider complex boundaries.

Drilling and pump testing to obtain local hydraulic properties and boundary conditions are planned during the first quarter of 2013. The numerical model will be set up after the drilling and pumping tests, using the new data for calibration. The numerical model will contain as much of the physical layer definitions and potential internal boundaries as possible with model boundaries incorporated along  far  field  fault  zones  and  hydraulic  boundaries.  The  numerical model  should  improve the reliability of estimates of pit inflow and water supply to the plant.

The results between the analytical and numerical approaches can then be compared to improve future dewatering estimates with limited data. It is expected that the reliability of the analytical predictions will reduce after year 4, where the role of boundaries are expected to influence the drawdowns and related flow towards the pit.

Abstract

Variability in both rainfall and raw water demands at South African mines and lack of accurate predictive planning tools often leads to water shortages or spillages of excess dirty water. The demand varies due to changing production rates, scheduled and unscheduled maintenance, while available water resources are greatly influenced by droughts and untimely storm events. Using averages in static water balances or planning for “worst case scenarios” by increasing storm water capacity or securing larger volumes from external sources “for in case”, is expensive and could still be inadequate.

A dynamic simulation model can integrate all the variables above with available ground- and surface water resources. Groundwater is  often underestimated as  a  source.  A  simulation model can  test  strategies to optimise its role before expensive dams or pipelines are considered.

In the case studies presented, Arena simulation software (from Rockwell) are used with hourly time steps to dynamically simulate water flows/levels, evaporation, seepage and rainfall runoff. All flows and dam levels are recorded to Excel for statistical analysis after simulation runs. To calculate the significance of overflow events and maximum demands the model runs multiple iterations which render specific confidence intervals for results, for example a 95% confidence level that a specific dam will not overflow more than once during the life of mine. Models may span several shafts, concentrator plants and smelter complexes. One model integrated over 1 000 flows and 75 dams with respective flow logic on the backdrop of a Google map of operations. Highlights of recent case studies include: 

• Groundwater from shallow anthropogenic aquifers greatly reduced external raw water requirements.
• This also prevented the clean water from overflowing into the underground workings where it is then pumped from depth as dirty water. 
• Artificial recharge of an aquifer with sporadic excess surface water increased the groundwater in storage that was used as a buffer for drought periods. 
• Optimised models proved that external raw water requirements and overflows into the environment could be significantly reduced and in some cases eliminated.

A dynamic water balance simulation model integrates business components with all related flows and storages and is the best tool available to accurately predict water resource demands and overflows to the environment. It enables the testing and optimization of water management strategies long before capital is spent and enhances the understanding, buy-in and decision support for all affected parties.

A picture is worth a thousand words... A (good) simulation is worth a thousand pictures!

Abstract

Accurate parameter estimation for fractured-rock aquifers is very challenging, due to the complexity of   fracture   connectivity,   particularly   when   it   comes   to   artesian   flow   systems   where   the potentiometric  is  above  the  ground  level,  such  as  semi-confined,  partially  confined  and  weak confined aquifers in Table Mountain Group (TMG) Aquifer. The parameter estimates of these types of aquifers are largely made through constant-head and recovery test methods. However, such tests are seldom carried out in the Table Mountain Group Aquifer in South Africa due to the lack of a proper testing unit made available for data capturing and an appropriate method for data interpretation. 

An artesian borehole of BH-1 drilled in TMG Peninsula Formation on the Gevonden farm in Western Cape Province was chosen as a case study. The potentiometric surface is above the ground level in the rainy season, while it drops to below ground level during the dry season. A special testing unit was designed and implemented in BH-1 to measure and record the flow rate during the free-flowing period, and the pressure changes during the recovery period. All the data were captured at a function of time for data interpretation at later stage. 

Curve-fitting software developed with VBA (Visual Basic Application) in Excel was adopted for parameter estimation based on the constant-head and recovery tests theories. The results indicate that a negative skin zone exists in the immediate vicinity of the artesian borehole in Rawsonville, and the  hydraulic  parameters  estimates  of  transmissivity  (T)  ranging  from  6.9  to  14.7 m2/d  and storativity  (S)  ranging  from  2.1×10-5   to  2.1×10-4   appear  to  be  reasonable  with  measured  data collected from early times. The effective radius is estimated to be 0.5 to 1.58 m. However, due to formation losses, the analytical method failed to interpret the data collected at later times. Consequently the analysed results by analytical solution with later stage data are less reliable for this case. Numerical modelling is proposed to address the issue in future.

Abstract

In recent years there is an increased awareness of hydrocarbon contamination in South Africa, and the need for remediating sites affected by these contaminants. Hydrocarbon contamination of groundwater can be caused by a large variety of activities at industrial, mining or residential areas. Once these contaminants are discovered in groundwater where it poses risks to human health and/or the environment, remediation is often required. Remediation of groundwater has become a booming industry for groundwater practitioners and often there is an attitude of more sophisticated and expensive solutions are better. This paper will show that this attitude is not always the best solution, but rather recommend an approach where a combination of low cost/low maintenance system need to be investigated and applied to reach clean-up goals. Determination of natural attenuation potential and on-going monitoring forms an integral part of this type of solution.

Abstract

Acid-mine drainage (AMD) has received considerable media coverage in South Africa as of late. This have caused a considerable increase in researches, most of them with emphasis on decanting of contaminated water from the old gold mines in Witwatersrand basins and fewer on mine residue contamination from coal and gold mines in the Mpumalanga Province. The paper outlines results of ground geophysical surveys that were carried out along the perimeter of two mine residual deposits (dumps) in the Barberton Greenstone Belt, Mpumalanga Province. The aim of the study was to generate a  3D geoelectric model of the subsurface showing possible acid-mine drainage contaminant pathways. Two geophysical methods, namely Frequency Domain Electromagnetic Profiling (FDEM) and Electrical Resistivity Tomography (ERT) were applied in order to investigate the variation of electrical conductivity in the subsurface. The ERT method was done over frequency domain electromagnetics anomalies.

FDEM electrical conductivity values ranging between 40 mS/m to 60 mS/m were considered as anomalous in that geological terrain. These areas were then surveyed by the ERT method to check the depth extent of these FDEM anomalies. On the resistivity section, between station 40 m and 80 m of Dump 1 – ERT1, a discontinuity in the bedrock was identified. The area could act as a pathway for contaminants to flow from the dump to groundwater. The FDEM survey identified an area with high conductivity values to the north of Dump 1. The ERT results also showed a shallow plume at 30 m depth which is consistent on two parallel sections on Dump 1. The area could be a possible AMD pathway of a mine dump residue to a Komati tributary on the north. The bedrock is generally characterised by high resistivity values; a break in the bedrock exists on this high resistivity zone on ERT 6. This break could be a fault zone which can act as possible pathway of (AMD) from a mine dump residue to a shallow aquifer.

Potential contaminant recharge pathways were delineated using geophysical, electrical and electromagnetic methods. Potential groundwater recharge pathways and sub-vertical low resistivity zones with values <100Ohm.m   were   delineated   using   the   ERT   method.   Investigation   of   contaminant   plume   migration   is recommended over the anomalies that were generated from geophysics data in the Barberton areas. New technologies (artificial neural networks (ANN), fuzzy logic, etc.) combined with laboratory studies is recommended for development of a software platform that accepts 3D geoelectric data (present study), constrained with geology, geochemistry (soil and water), hydrology and hydrogeology data.